Transfer game/chars to new steam account

Hello!

Love the game so far, about 170 hours in.

Predicament: my wife has taken up gaming and I bought her a bunch of games on my steam account (big mistake I know, she should have made her own). Now we can’t play at the same time, and I can’t get a refund on the games I bought her at this point. I was wondering if I create a new steam account if LE would assist me in transferring my account (my online characters + stash + progress etc)? I have no issues repurchasing the game, I just don’t want to start from complete scratch. Just figured I’d ask here before I explored any alternative options. Thanks and keep up the good work LE.