Isadora's Set for Acolyte

There’s a pair of set noble gloves called Isadora’s Gravechill. I thought chill would freeze the enemy or maybe I am wrong? It says 100% chance to chill with necrotic abilities if you killed an enemy in the last 5 seconds. I have used hungering souls and spirit plague. They are not freezing. I also have the 2 set bonus. Not sure if the “100% chance to apply damned on hit with necrotic spells” works or not. So, please explain what’s going on.

Thanks!

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